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The Green Bank Telescope (GBT) Diffuse Ionized Gas Survey (GDIGS) traces ionized gas in the Galactic midplane by observing radio recombination line (RRL) emission from 4–8 GHz. The nominal survey zone is 32.3° > l > -5°, |b| < 0.5°. Here, we analyze GDIGS Hnα ionized gas emission toward discrete sources with sizes comparable to the 2.065' GDIGS Hnα beam. We use GDIGS data to identify the correct velocity of 39 H II regions that have multiple RRL velocity components. We identify and characterize RRL emission from 88 H II regions that previously lacked measured ionized gas velocities. We additionally identify and characterize RRL emission from eight locations that appear to be previously-unidentified H II regions and 41 locations of RRL emission that do not appear to be H II regions based on their lack of mid-infrared emission. We identify 10 discrete sources that have anomalously high RRL velocities for their locations in the Galactic plane and we compare the objects’ RRL data to 13CO, H I and mid-infrared data. These sources do not have the expected 24 μm emission characteristic of H II regions. Based on this comparison we do not think these objects are H II regions, but we are unable to classify them as a known type of object.